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Definition
and history of the Earth's atmosphere
An atmosphere is defined as the gaseous envelope
that surrounds a celestial body. Therefore, the Earth,
like other planets in the solar system, has an atmosphere,
which is retained by gravitational attraction and
largely rotates with it.
Compared with the radius of the Earth, its atmosphere
is very thin. 99% of the mass of the atmosphere lies
below 30 km, or 0.5% of the equatorial radius.
Meteorology is the subject that studies the chemical
and physical properties of the atmosphere together
with its fields of motion, mass and moisture.
At the time of the Earth's formation around 4.5 billion
years ago there was probably no atmosphere. It is
believed to have come into existence as a result of
the volcanic expulsion of substances from its interior,
ejecting mainly water vapour, with some carbon dioxide,
nitrogen and sulphur. The atmosphere can only hold
a certain amount of water vapour, so the excess condensed
into liquid water to form the oceans.
It is thought that the first stage in the evolution
of life, around 4,000,000,000 years ago, required
an oxygen-free environment. At a later date, primitive
forms of plant life developed in the oceans and began
to release small amounts of oxygen into the atmosphere
as a waste product from the cycle of photosynthesis,
as shown by the following equation.
H2O + CO2 +
sunlight → sugar + O2
This build-up of atmospheric oxygen eventually led
to the formation of the ozone layer. This layer, approximately
8 to 30 km above the surface, helps to filter the
ultraviolet portion of the incoming solar radiation
spectrum. Therefore, as levels of harmful ultraviolet
radiation decreased, so plants were able to move to
progressively higher levels in the oceans.
This helped to boost photosynthesis and thereby the
production of oxygen. Today, this element has reached
levels where life has been sustainable on the surface
of the planet through its presence, and it should
be remembered that oxygen is an element which is not
commonly found in the universe.
The composition
of the atmosphere
The atmosphere is well mixed below 100 km, and apart
from its highly variable water vapour and ozone contents,
its composition is as shown below, excluding solid
and liquid matter in suspension (aerosols).
| COMPOSITION
OF THE ATMOSPHERE |
|
Gas
|
Symbol
|
% by weight
|
% by volume
|
|
Nitrogen
|
N2
|
75.52
|
78.09
|
|
Oxygen
|
O2
|
23.15
|
20.95
|
|
Argon
|
A
|
1.28
|
0.93
|
|
Carbon dioxide
|
CO2
|
0.046
|
0.035
|
|
Neon
|
Ne
|
0.012
|
0.0018
|
|
Helium
|
He
|
0.0007
|
0.0005
|
|
Methane
|
CH4
|
0.0008
|
0.00015
|
|
Krypton
|
Kr
|
0.003
|
0.0001
|
|
Ozone
|
O3
|
0-0.01
|
Variable
|
|
Water vapour
|
H20
|
0-4
|
Variable
|
|
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| The vertical
structure of the atmosphere |
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The Earth's atmosphere is most commonly divided into
four isothermal layers or 'spheres': troposphere,
stratosphere, mesosphere and thermosphere.
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Fig 1: Vertical temperature profile
of the ICAO Standard Atmosphere
Each layer is characterised by a uniform change
in temperature with increasing altitude. In
some layers there is an increase in temperature
with altitude, whilst in others it decreases
with increasing altitude. The top or boundary
of each layer is denoted by a 'pause' where
the temperature profile abruptly changes, as
shown in Figure 1.
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Troposphere
The troposphere contains about 80% of the atmosphere
and is the part of the atmosphere in which we live,
and make weather observations. In this layer, average
temperatures decrease with height. This is known as
adiabatic cooling, i.e. a change in temperature caused
by a decrease in pressure. Even so, it is still more
prone to vertical mixing by convective and turbulent
transfer, than other parts of the atmosphere. These
vertical motions and the abundance of water vapour
make it the home of all important weather phenomena.
The troposphere's thermal profile is largely the
result of the heating of the Earth's surface by incoming
solar radiation. Heat is then transferred up through
the troposphere by a combination of convective and
turbulent transfer. This is in direct contrast with
the stratosphere, where warming is the result of the
direct absorption of solar radiation.
The troposphere is around 16 km high at the equator,
with the temperature at the tropopause around –80
°C. At the poles, the troposphere reaches a height
of around 8 km, with the temperature of the tropopause
around –40 °C in summer and –60 °C in winter.
Therefore, despite the higher surface temperatures,
the tropical tropopause is much cooler than at the
poles.
Stratosphere
In contrast to the troposphere, temperatures in the
stratosphere rise with increasing altitude. Another
distinctive feature of the stratosphere is the absorption
of ultraviolet radiation by ozone (O3).
This is greatest around 50 km, which is where the
stratopause occurs. Temperatures reach a maximum here,
and according to latitude and season, they range from
–30 °C over the winter pole to +20 °C over the summer
pole.
As well as a noticeable change in temperature, the
move from the troposphere into the stratosphere is
also marked by an abrupt change in the concentrations
of the variable trace constituents. Water vapour decreases
sharply, whilst ozone concentrations increase. These
strong contrasts in concentrations are a reflection
of little mixing between the moist, ozone-poor troposphere
and the dry, ozone-rich stratosphere.
Despite the dryness of the stratosphere, some clouds
have developed in winter months over high latitudes
at altitudes between 17 and 30 km, stretching into
the stratosphere. They generally display iridescence
and are known as nacreous clouds.
The stratosphere extends up to around 48 km above
the surface, and together with the troposphere, they
account for 99.9% of the Earth's atmosphere.
Mesosphere
Temperatures in the mesosphere decrease with height
from the stratopause up to the mesopause, at around
85 km. Temperatures at the mesopause vary from as
low as –120 °C at high latitudes in summer to –50
°C in winter. The cold summer temperatures and the
warm winter temperatures are therefore a reverse of
what happens at the stratopause.
As in the troposphere, the unstable profile means
that the vertical motions are not inhibited. During
the summer, there is enough lifting to produce clouds
in the upper mesosphere at high latitudes – it is
then that the stratopause achieves its highest temperature
due to the optimum amount of solar radiation being
received. These clouds are known as noctilucent,
and are very thin. Even so, they are visible against
a night sky when the sun is at a small angle below
the horizon, so that they are high enough to be in
sunlight. By using triangulation techniques, these
clouds have been estimated to form up to 80 km above
the surface.
Thermosphere
The thermosphere extends upwards to altitudes of
several hundred kilometres, where temperatures range
from 500 K to as high as 2,000 K (Kelvin), depending
on the degree of solar activity. The temperature changes
between day and night amount to hundreds of degrees.
The height of the thermopause varies from about 200
to 500 km, again depending on solar activity. Above
500 km temperatures are very difficult to define.
Molecules are so widely spaced that they move independently,
and there is no reason why their temperatures should
be the same.
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Fig 2: Vertical temperature distribution
in the Earth's atmosphere (After P.M. Banks
and G. Kockarts)
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| Unequal
heating of the Earth's surface |
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The relationship between the Earth
and the Sun
There are many reasons which explain the unequal
or differential heating from pole to pole of the Earth's
surface. The principal factor is the change in the
Sun's elevation due to the latitude and season. The
Earth orbits the Sun approximately every 365 days.
The Earth also rotates on its own axis once every
24 hours, giving us our daily and diurnal variation.
As the Earth orbits the Sun, we get seasonal variations
which result from changes in the amount of solar radiation
reaching each part of the Earth, hence the variation
between daylight and darkness throughout the year.
The Earth's rotational axis is not vertical, but
tilted at an angle of 23.5° to the vertical. Because
of this the apparent motion of the overhead sun appears
to move from the Tropic of Cancer (23.5° N) at northern
hemisphere midsummer (21–22 June) to the Tropic of
Capricorn (23.5° S) at northern mid winter (21-22
December). Summer/winter alternate as the northern
and southern hemispheres are alternately tilted towards/away
from the Sun.
Fig 3: Annual movement of
the Earth around the Sun
If the Earth did not tilt on its axis, there would
be no seasons at all, and most places, except the
poles, would have 12 hours daylight each day throughout
the year.
Every year the polar areas have at least one complete
24-hour period of darkness and one of daylight. In
theory, the poles themselves should have six months
of daylight followed by six months of darkness. In
reality, this is not the case because some light from
the Sun is bent towards the Earth making nights slightly
shorter than they otherwise would be.
The equatorial regions do not really have seasons
as we know them, as the relative position of the overhead
Sun does not change significantly enough throughout
the year.
At high latitudes the Sun's rays reach the Earth's
surface more obliquely, so that the energy is spread
over a greater surface area. In addition, more radiation
is lost to scattering and absorption as the path through
the atmosphere is longer. In the winter at high latitudes,
days are short with continuous darkness in polar regions
at mid-winter. Here there is a net loss of outgoing
long-wave radiation into space with no incoming short-wave
radiation to compensate. Nearer the equator, where
the sun is near the vertical, at midday the sun's
rays strike with greater intensity, as shown in Figure
4.
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Fig 4: The Sun's energy is more concentrated
per unit area in A than it is in B
A and B are equal and parallel clusters of
light rays from the Sun. At A the Sun is overhead
and the rays are at right angles to the atmosphere
and the surface of the Earth. At B the rays
approach the atmosphere from an angle and consequently
have more atmosphere to travel through - distance
A compared with distance B on Figure 4. Also,
being at an angle illuminates a larger surface
area of the Earth's surface. Effectively the
energy arriving has to be distributed over a
greater area from source B compared with source
A.
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Effective
use of incoming radiation
Another contributory factor in determining the weather
and climate is the amount of the Sun's energy which
is absorbed by the Earth's surface. The amount of
reflection by the Earth's surface is known as albedo.
The lower the albedo of a particular surface the more
solar radiation is absorbed. The polar ice sheets
reflect incoming short-wave radiation so effectively
that there is little heat available for a rise in
temperature. Deserts, on the other hand, reflect only
about 25% of radiation from the Sun and consequently
the high rate of absorption means they can get very
hot.
| TYPICAL
ALBEDOS (%) |
| Surface type |
Albedo |
| Water (solar
elevation 90°) |
3 |
| Water
(solar elevation 30°) |
7 |
| Water (solar
elevation 10°) |
24 |
| Sea
ice |
30-40 |
| Fresh snow |
75-95 |
| Old
snow |
55 |
| Forests |
5-10 |
| Dry
sand |
20-30 |
| Dark soil |
5-15 |
| Grassland |
15-20 |
| Thin cloud |
35-50 |
| Thick
cloud |
70-90 |
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The amount of albedo can also depend on the angle
of the Sun's rays. For example when the Sun is high
in the sky, the sea absorbs much of the radiation,
when it is low in the sky the sea acts rather like
a mirror, reflecting most of the incoming radiation.
More solar radiation reaches the atmosphere above
the summer pole during the continuous daylight period
than reaches the atmosphere at the equator. The high
albedo and low angle of the sun ensure that this is
spread out over a larger angle than at the equator,
reducing its heating effect, and a significant proportion
of what reaches the surface is reflected back into
space. Total planetary albedo is estimated at around
40%, so four tenths of the incoming radiation is reflected
back into space.
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The next question which needs answering is why do
the poles get colder and colder, whilst the equator
gets hotter and hotter? The answer involves the presence
of water and the general circulation of air.
Water
Without water in the atmosphere there would be no
weather, no rain, no snow, or even clouds. Water,
in the form of water vapour in the atmosphere, or
currents in the ocean is responsible for transferring
heat energy from the equator towards the poles.
Water is the only substance to occur naturally in
the atmosphere as either a solid (ice), liquid (water,
rain) and a gas (water vapour). The energy absorbed
and released during its changes from one state to
another is the main method of energy transfer in the
atmosphere.
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High temperatures over the equator and low temperatures
over the poles result in a series of circulatory cells
which form part of a theory known as the tricellular
model. There is an added complication to this model
in that the Earth is rotating. This has the effect
of splitting the circulation between the equator and
the poles into three cell zones – the Hadley, Ferrel
and Polar (see Figure 5).
Within the equatorial region, surface air rises and
flows towards the poles. At about 30° latitude, the
air starts to descend, with the returning branch flowing
at the surface toward the equator. However, the Coriolis
force acts upon this surface flow, deflecting the
air to the right (east) in the northern hemisphere
and to the left (west) in the southern hemisphere.
The resulting surface winds are named the trade winds,
because of the important role they played in opening
up the New World to trade. The cell in the tri-cellular
model, closest to the equator, is named after the
English meteorologist, George Hadley (1685–1768) who
first postulated the existence of the cell to explain
these trade winds. In doing so, he clearly recognised
the importance of what much later was to be named
the Coriolis force.
Between the Hadley cell and the Polar cell is the
Ferrel Cell – named after William Ferrel, an American
meteorologist. This cell lies between about 30° to
about 60° latitude, and it is not directly thermally
driven (as it is in the opposite direction to the
Hadley cell and the Polar cell). It represents an
area of cyclonic disturbances that intermittently
transport heat and westerly momentum between the tropical
cell and polar regions. The British Isles lie within
the area of influence of the Ferrel cell.
| Fig 5: Idealised representation
of the general circulation of the atmosphere showing
the positions of Polar Front; ITCZ (Inter Tropical
Convergence Zone); Subtropical Jets (STJ) Polar
Front Jets (PFJ) |
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Low pressure regions exist at points where air
rises. These occur where:
- warm air ascends in equatorial regions,
giving rise to the slack equatorial low;
- Ferrel and Polar cells meet, producing
an area of low pressure. This convergence
of the polar north-easterlies and mid-latitude
south-westerlies with a subtropical origin
produces the polar front, which is highly
variable in its day-to-day position.
High pressure occurs where air descends. There
are two main areas of descending air, compensating
for the rising air of low pressure.
- In polar regions, which give rise to the
polar high pressure area
- In subtropical regions which give rise to
the subtropical high-pressure belt
In both regions, the amounts of precipitation
are rather small. The hot deserts are to be
found in the region of the subtropical high,
whilst the polar regions are rather dry because
evaporation is rather slow and precipitation
remains on the ground for some time.
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1. Define the term 'atmosphere'.
2. Explain how photosynthesis allowed
the initial release of oxygen, allowing
the Earth's atmosphere to form.
3. What is ozone? What important role
does it perform?
4. Which of the following are the two
major gases in the Earth's atmosphere
– nitrogen, hydrogen, oxygen, methane
or carbon dioxide?
5. Arrange the following atmospheric
layers into the correct order, starting
with the layer, nearest the Earth's surface
– mesosphere, stratosphere, troposphere,
thermosphere.
6. What is meant by the term 'adiabatic
cooling'?
7. How high is the troposphere over the
equator – 4, 8, 16 or 32 km?
8. Do temperatures increase, or decrease
with increasing altitude, in the stratosphere?
9. How high is the troposphere over the
poles – 4, 8, 16 or 32 km?
10. Explain the differences between nacreous
and noctilucent clouds.
11. Describe how the Earth's tilt and
rotational axis causes differences in
the amount of heat received at the Earth's
surface.
12. What is albedo? How does it vary
with different types of surface?
13. What are trade winds?
14. Describe the factors which cause:
(a) high pressure,
and
(b) low pressure.
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